Publications of Fabio P. Caló

Peeters, M.; Baldinelli, L.; Leutzsch, M.; Caló, F. P.; Auer, A. A.; Bistoni, G.; Fürstner, A. In Situ Observation of Elusive Dirhodium Carbenes and Studies on the Innate Role of Carboxamidate Ligands in Dirhodium Paddlewheel Complexes: A Combined Experimental and Computational Approach. Journal of the American Chemical Society 2024, 146, 26466–26477.

Gui, X.; Sorbelli, D.; Caló, F. P.; Leutzsch, M.; Patzer, M.; Fürstner, A.; Bistoni, G.; Auer, A. A. Elucidating the Electronic Nature of Rh-Based Paddlewheel Catalysts from ¹⁰³Rh NMR Chemical Shifts: Insights from Quantum Mechanical Calculations. Chemistry – A European Journal 2024, 30, e202301846.

Caló, F. P.; Zimmer, A.; Bistoni, G.; Fürstner, A. From Serendipity to Rational Design: Heteroleptic Dirhodium Amidate Complexes for Diastereodivergent Asymmetric Cyclopropanation. Journal of the American Chemical Society 2022, 144, 7465–7478.

Caló, F. P.; Bistoni, G.; Auer, A. A.; Leutzsch, M.; Fürstner, A. Triple Resonance Experiments for the Rapid Detection of ¹⁰³Rh NMR Shifts: A Combined Experimental and Theoretical Study into Dirhodium and Bismuth–Rhodium Paddlewheel Complexes. Journal of the American Chemical Society 2021, 143, 12473–12479.

Löffler, L. E.; Buchsteiner, M.; Collins, L. R.; Caló, F. P.; Singha, S.; Fürstner, A. [Rh₂(MEPY)₄] and [BiRh(MEPY)₄]: Convenient Syntheses and Computational Analysis of Strikingly Dissimilar Siblings. Helvetica Chimica Acta 2021, 104, e2100042.

Caló, F. P.; Fürstner, A. A Heteroleptic Dirhodium Catalyst for Asymmetric Cyclopropanation with α‐Stannyl α‐Diazoacetate. "Stereoretentive" Stille Coupling with Formation of Chiral Quarternary Carbon Centers. Angewandte Chemie International Edition 2020, 59, 13900–13907.

Caló, F. P. Heteroleptische Dirhodium(II)-Komplexe und ihre Rolle als Katalysatoren in der Asymmetrischen Cyclopropanierung mit α-Metallierten Diazoverbindungen. PhD Thesis, Technische Universität Dortmund, Dortmund, 2022.

Caló, F. P. Dirhodium Carbenes - The Structure and Stability of Chiral Dirhodium Carbenes & α-Silyl Diazo Compounds as Sequential Cylopropanation/Cross-Coupling Reagents. Master's Thesis, Ruhr-Universität Bochum, Bochum, 2018.