Publications of Markus Leutzsch

Han, J. T.; Tsuji, N.; Zhou, H.; Leutzsch, M.; List, B. Organocatalytic Asymmetric Synthesis of Si-Stereogenic Silacycles. Nature Communications 2024, 15, 5846.

Schulte, T.; Wang, Z.; Li, C.-C.; Hamad, A.; Waldbach, F.; Pampel, J.; Petzold, R.; Leutzsch, M.; Bahns, F.; Ritter, T. Ruthenium Phenoxo Complexes: An Isolobal Ligand to Cp with Improved Properties. Journal of the American Chemical Society 2024, 146, 15825–15832.

Spinnato, D.; Leutzsch, M.; Wang, F.; Cornella, J. Internal Atom Exchange in Oxazole Rings: A Blueprint for Azole Scaffold Evaluation. Synlett 2024, 35, 1015–1018.

Rütter, D.; van Gastel, M.; Leutzsch, M.; Nöthling, N.; SantaLucia, D.; Neese, F.; Fürstner, A. Molybdenum(VI) Nitrido Complexes with Tripodal Silanolate Ligands. Structure and Electronic Character of an Unsymmetrical Dimolybdenum μ-Nitrido Complex Formed by Incomplete Nitrogen Atom Transfer. Inorganic Chemistry 2024, 63, 8376–8389.

Mateos, J.; Schulte, T.; Behera, D.; Leutzsch, M.; Altun, A.; Sato, T.; Waldbach, F.; Schnegg, A.; Neese, F.; Ritter, T. Nitrate Reduction Enables Safer Aryldiazonium Chemistry. Science 2024, 384, 446–452.

Gui, X.; Sorbelli, D.; Caló, F. P.; Leutzsch, M.; Patzer, M.; Fürstner, A.; Bistoni, G.; Auer, A. A. Elucidating the Electronic Nature of Rh-Based Paddlewheel Catalysts from ¹⁰³Rh NMR Chemical Shifts: Insights from Quantum Mechanical Calculations. Chemistry – A European Journal 2024, 30, e202301846.

Wakchaure, V. N.; DeSnoo, W.; Laconsay, C. J.; Leutzsch, M.; Tsuji, N.; Tantillo, D. J.; List, B. Catalytic Asymmetric Cationic Shifts of Aliphatic Hydrocarbons. Nature 2024, 625, 287–292.

Harbor-Collins, H.; Sabba, M.; Bengs, C.; Moustafa, G.; Leutzsch, M.; Levitt, M. H. NMR Spectroscopy of a ¹⁸O-Labeled Rhodium Paddlewheel Complex: Isotope Shifts, ¹⁰³Rh–¹⁰³Rh Spin–Spin Coupling, and ¹⁰³Rh Singlet NMR. The Journal of Chemical Physics 2024, 160, 014305.

Korber, J. N.; Wille, C.; Leutzsch, M.; Fürstner, A. From the Glovebox to the Benchtop: Air-Stable High Performance Molybdenum Alkylidyne Catalysts for Alkyne Metathesis. Journal of the American Chemical Society 2023, 145, 26993–27009.

Moon, H. W.; Wang, F.; Bhattacharyya, K.; Planas, O.; Leutzsch, M.; Nöthling, N.; Auer, A. A.; Cornella, J. Mechanistic Studies on the Bismuth-Catalyzed Transfer Hydrogenation of Azoarenes. Angewandte Chemie International Edition 2023, 62, e202313578.

Tsuruta, T.; Spinnato, D.; Moon, H. W.; Leutzsch, M.; Cornella, J. Bi-Catalyzed Trifluoromethylation of C(Sp²)–H Bonds under Light. Journal of the American Chemical Society 2023, 145, 25538–25544.

Singh, V. K.; Zhu, C.; De, C. K.; Leutzsch, M.; Baldinelli, L.; Mitra, R.; Bistoni, G.; List, B. Taming Secondary Benzylic Cations in Catalytic Asymmetric S_N1 Reactions. Science 2023, 382, 325–329.

Palme, P. R.; Goddard, R.; Leutzsch, M.; Richter, A.; Imming, P.; Seidel, R. W. Structural Elucidation of the Triethylammonium Betaine of Squaric Acid. Molbank 2023, 2023, M1737.

Harbor-Collins, H.; Sabba, M.; Moustafa, G.; Legrady, B.; Soundararajan, M.; Leutzsch, M.; Levitt, M. H. The ¹⁰³Rh NMR Spectroscopy and Relaxometry of the Rhodium Formate Paddlewheel Complex. The Journal of Chemical Physics 2023, 159, 104307.

Mato, M.; Bruzzese, P. C.; Takahashi, F.; Leutzsch, M.; Reijerse, E. J.; Schnegg, A.; Cornella, J. Oxidative Addition of Aryl Electrophiles into a Red-Light-Active Bismuthinidene. Journal of the American Chemical Society 2023, 145, 18742–18747.

Lindner, M. M.; Alachraf, M. W.; Mitschke, B.; Schulze, P.; Leutzsch, M.; List, B. Toward a Formyl-to-Phenyl Conversion: An Unexpected Photochemical Fulvene-Rearrangement. Angewandte Chemie International Edition 2023, 62, e202303119.

Schwengers, S. A.; Gerosa, G. G.; Amatov, T.; Yasukawa, N.; Brunen, S.; Leutzsch, M.; Mitschke, B.; Shevchenko, G. A.; List, B. Direct Regioselective Dehydrogenation of α-Substituted Cyclic Ketones. Angewandte Chemie International Edition 2023, 62, e202307081.

Pang, Y.; Leutzsch, M.; Nöthling, N.; Cornella, J. Dihydrogen and Ethylene Activation by a Sterically Distorted Distibene. Angewandte Chemie International Edition 2023, 62, e202302071.

Yang, X.; Kuziola, J.; Béland, V. A.; Busch, J.; Leutzsch, M.; Burés, J.; Cornella, J. Bismuth-Catalyzed Amide Reduction. Angewandte Chemie International Edition 2023, 62, e202306447.

Mato, M.; Spinnato, D.; Leutzsch, M.; Moon, H. W.; Reijerse, E. J.; Cornella, J. Bismuth Radical Catalysis in the Activation and Coupling of Redox-Active Electrophiles. Nature Chemistry 2023, 15, 1138–1145.