Publications
Journal Article (52)
2024
Journal Article
van Gastel, M.; ; Understanding the P-Cluster of Vanadium Nitrogenase: an EPR and XAS Study of the Holo Vs. Apo Forms of the Enzyme. ChemBioChem: A European Journal of Chemical Biology 2024, e202400833.
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Journal Article
van Gastel, M.; ; ; A Four-Coordinate End-On Superoxocopper(II) Complex: Probing the Link between Coordination Number and Reactivity. Journal of the American Chemical Society 2024, 146, 23704–23716.
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Journal Article
Rütter, D.; van Gastel, M.; Leutzsch, M.; Nöthling, N.; ; Neese, F.; Fürstner, A. Molybdenum(VI) Nitrido Complexes with Tripodal Silanolate Ligands. Structure and Electronic Character of an Unsymmetrical Dimolybdenum μ-Nitrido Complex Formed by Incomplete Nitrogen Atom Transfer. Inorganic Chemistry 2024, 63, 8376–8389.
Journal Article
Spinnato, D.; Nöthling, N.; Leutzsch, M.; van Gastel, M.; Wagner, L.; Neese, F.; Cornella, J. A Trimetallic Bismuth-Based Allyl Cation. ChemRxiv: the Preprint Server for Chemistry 2024.
2023
Journal Article
SantaLucia, D. J.; van Gastel, M.; ; ; ; ; Reactivities and Electronic Structures of μ-1,2-Peroxo and μ-1,2-Superoxo CoIIICoIII Complexes: Electrophilic Reactivity and O2 Release Induced by Oxidation. Inorganic Chemistry 2023, 62, 17913–17930.
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Journal Article
van Gastel, M.; ; ; Synthesis and Reactivity of a Cobalt-Supported Singlet Nitrene. Journal of the American Chemical Society 2023, 145, 13650–13662.
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Journal Article
Pang, Y.; Nöthling, N.; Leutzsch, M.; ; ; van Gastel, M.; ; Goddard, R.; Wagner, L.; SantaLucia, D. J.; ; Neese, F.; Cornellà, J. Synthesis and Isolation of a Triplet Bismuthinidene with a Quenched Magnetic Response. Science 2023, 380, 1043–1048.
Journal Article
van Gastel, M.; ; ; Crystalline Anions Based on Classical N-Heterocyclic Carbenes. Angewandte Chemie International Edition 2023, 62, e202215244.
; ; ; ; ; 2022
Journal Article
Pang, Y.; Nöthling, N.; Leutzsch, M.; ; ; van Gastel, M.; ; Goddard, R.; Wagner, L.; SantaLucia, D.; ; Neese, F.; Cornella, J. A “Non-Magnetic” Triplet Bismuthinidene Enabled by Relativity. ChemRxiv: the Preprint Server for Chemistry 2022.
Journal Article
van Gastel, M.; ; ; ; Umpolung in a Pair of Cobalt(III) Terminal Imido/Imidyl Complexes. Angewandte Chemie International Edition 2022, 61, e202206848.
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Journal Article
Chatterjee, S.; Harden, I.; Bistoni, G.; ; Chabbra, S.; van Gastel, M.; Schnegg, A.; Bill, E.; Birrell, J. A.; Morandi, B.; Neese, F.; DeBeer, S. A Combined Spectroscopic and Computational Study on the Mechanism of Iron-Catalyzed Aminofunctionalization of Olefins Using Hydroxylamine Derived N–O Reagent as the “Amino” Source and “Oxidant.” Journal of the American Chemical Society 2022, 144, 2637–2656.
2021
Journal Article
van Gastel, M.; ; Sterically Stabilized End-On Superoxocopper(II) Complexes and Mechanistic Insights into Their Reactivity with O–H, N–H, and C–H Substrates. Journal of the American Chemical Society 2021, 143, 19731–19747.
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Journal Article
Haack, A.; Hillenbrand, J.; van Gastel, M.; Fürstner, A.; Neese, F. Spectroscopic and Theoretical Study on Siloxy-Based Molybdenum and Tungsten Alkylidyne Catalysts for Alkyne Metathesis. ACS Catalysis 2021, 11, 9086–9101.
Journal Article
Schulz, C. E.; van Gastel, M.; Pantazis, D. A.; Neese, F. Converged Structural and Spectroscopic Properties for Refined QM/MM Models of Azurin. Inorganic Chemistry 2021, 60, 7399–7412.
Journal Article
Haack, A.; Hillenbrand, J.; Leutzsch, M.; van Gastel, M.; Neese, F.; Fürstner, A. Productive Alkyne Metathesis with “Canopy Catalysts” Mandates Pseudorotation. Journal of the American Chemical Society 2021, 143, 5643–5648.
Journal Article
van Gastel, M.; ; Metalloradical Cations and Dications Based on Divinyldiphosphene and Divinyldiarsene Ligands. Chemistry – A European Journal 2021, 27, 5803–5809.
; ; ; ; ; ; 2020
Journal Article
Hillenbrand, J.; van Gastel, M.; Bill, E.; Neese, F.; Fürstner, A. Isolation of a Homoleptic Non-Oxo Mo(V) Alkoxide Complex: Synthesis, Structure and Electronic Properties of Penta-Tert-Butoxymolybdenum. Journal of the American Chemical Society 2020, 142, 16392–16402.
Journal Article
van Gastel, M.; ; ; Ye, S.; A Manganese(IV)-Hydroperoxo Intermediate Generated by Protonation of the Corresponding Manganese(III)-Superoxo Complex. Journal of the American Chemical Society 2020, 142, 10255–10260.
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Journal Article
van Gastel, M.; Isolation of Singlet Carbene Derived 2-Arsa-1,3-Butadiene Radical Cations and Dications. Chemical Communications 2020, 56, 3575–3578.
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Journal Article
van Gastel, M.; Isolation of Singlet Carbene Derived 2-Phospha-1,3-Butadienes and their Sequential One-Electron Oxidation to Radical Cations and Dications. Chemical Science 2020, 11, 1975–1984.
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