Publikationen der NMR-Abteilung

Scharf, M. J.; Tsuji, N.; Lindner, M. M.; Leutzsch, M.; Lõkov, M.; Parman, E.; Leito, I.; List, B.: Highly Acidic Electron-Rich Brønsted Acids Accelerate Asymmetric Pictet–Spengler Reactions by Virtue of Stabilizing Cation–π Interactions. Journal of the American Chemical Society (2024)

Kuziola, J.; Nöthling, N.; Leutzsch, M.; Cornella, J.: Synthesis and characterization of chlorotriarylbismuthonium salts. Chemical Communications 60 (76), S. 10532 - 10535 (2024)

Chugh, V.; Wu, J.; Leutzsch, M.; Randel, H.; Weyhermüller, T.; Auer, A. A.; Farès, C.; Werlé, C.: Controlling hydrogen transfer dynamics in adaptive semihydrogenation of alkynes: Unveiling and directing outer- vs. inner-sphere mechanisms. Chem Catalysis 4 (9), 101078 (2024)

Béland, V. A.; Nöthling, N.; Leutzsch, M.; Cornella, J.: Activation and Catalytic Degradation of SF₆ and PhSF₅ at a Bismuth Center. Journal of the American Chemical Society 146 (37), S. 25409 - 25415 (2024)

Lin, D. S.; Späth, G.; Meng, Z.; Wieske, L. H. E.; Farès, C.; Fürstner, A.: Total Synthesis of the Norcembranoid Scabrolide B and Its Transformation into Sinuscalide C, Ineleganolide, and Horiolide. Journal of the American Chemical Society 146 (35), S. 24250 - 24256 (2024)

Harbor-Collins, H.; Sabba, M.; Leutzsch, M.; Levitt, M. H.: ¹H-enhanced ¹⁰³Rh NMR spectroscopy and relaxometry of ¹⁰³Rh(acac)₃ in solution. Magnetic Resonance 5 (2), S. 121 - 129 (2024)

Luo, N.; Turberg, M.; Leutzsch, M.; Mitschke, B.; Brunen, S.; Wakchaure, V. N.; Nöthling, N.; Schelwies, M.; Pelzer, R.; List, B.: The catalytic asymmetric polyene cyclization of homofarnesol to ambrox. Nature 632, S. 795 - 801 (2024)

Zheng, T.; Nöthling, N.; Wang, Z.; Mitschke, B.; Leutzsch, M.; List, B.: A solid noncovalent organic double-helix framework catalyzes asymmetric [6 + 4] cycloaddition. Science 385 (6710), S. 765 - 770 (2024)

Karam, L.; Farès, C.; Weidenthaler, C.; Neumann, C. N.: Expedited Synthesis of Metal Phosphides Maximizes Dispersion, Air Stability, and Catalytic Performance in Selective Hydrogenation. Angewandte Chemie International Edition 63 (33), e202404292 (2024)

Han, J. T.; Tsuji, N.; Zhou, H.; Leutzsch, M.; List, B.: Organocatalytic asymmetric synthesis of Si-stereogenic silacycles. Nature Communications 15, 5846 (2024)

Schulte, T.; Wang, Z.; Li, C.-C.; Hamad, A.; Waldbach, F.; Pampel, J.; Petzold, R.; Leutzsch, M.; Bahns, F.; Ritter, T.: Ruthenium Phenoxo Complexes: An Isolobal Ligand to Cp with Improved Properties. Journal of the American Chemical Society 146 (23), S. 15825 - 15832 (2024)

Spinnato, D.; Leutzsch, M.; Wang, F.; Cornella, J.: Internal Atom Exchange in Oxazole Rings: A Blueprint for Azole Scaffold Evaluation. Synlett 35 (9), S. 1015 - 1018 (2024)

Rütter, D.; van Gastel, M.; Leutzsch, M.; Nöthling, N.; SantaLucia, D.; Neese, F.; Fürstner, A.: Molybdenum(VI) Nitrido Complexes with Tripodal Silanolate Ligands. Structure and Electronic Character of an Unsymmetrical Dimolybdenum μ-Nitrido Complex Formed by Incomplete Nitrogen Atom Transfer. Inorganic Chemistry 63 (18), S. 8376 - 8389 (2024)

Mateos, J.; Schulte, T.; Behera, D.; Leutzsch, M.; Altun, A.; Sato, T.; Waldbach, F.; Schnegg, A.; Neese, F.; Ritter, T.: Nitrate reduction enables safer aryldiazonium chemistry. Science 384 (6694), S. 446 - 452 (2024)

Spinnato, D.; Nöthling, N.; Leutzsch, M.; van Gastel, M.; Wagner, L.; Neese, F.; Cornella, J.: A trimetallic bismuth-based allyl cation. ChemRxiv: the Preprint Server for Chemistry (2024)

Hartmann, P.; Bohdan, K.; Hommrich, M.; Juliá, F.; Vogelsang, L.; Eirich, J.; Zangl, R.; Farès, C.; Jacobs, J. B.; Mukhopadhyay, D. et al.; Mengeler, J. M.; Vetere, A.; Sterling, M. S.; Hinrichs, H.; Becker, S.; Morgner, N.; Schrader, W.; Finkemeier, I.; Dietz, K.-J.; Griesinger, C.; Ritter, T.: Chemoselective umpolung of thiols to episulfoniums for cysteine bioconjugation. Nature Chemistry 16, S. 380 - 388 (2024)

Gehrke, L.; Bläker, C.; Pasel, C.; Farès, C.; Bathen, D.: Structural and energetic characterization of silica-alumina gels for adsorption processes. Microporous and Mesoporous Materials 365 (2), 112891 (2024)

Gui, X.; Sorbelli, D.; Caló, F. P.; Leutzsch, M.; Patzer, M.; Fürstner, A.; Bistoni, G.; Auer, A. A.: Elucidating the Electronic Nature of Rh-based Paddlewheel Catalysts from ¹⁰³Rh NMR Chemical Shifts: Insights from Quantum Mechanical Calculations. Chemistry – A European Journal 30 (4), e202301846 (2024)

Wakchaure, V. N.; DeSnoo, W.; Laconsay, C. J.; Leutzsch, M.; Tsuji, N.; Tantillo, D. J.; List, B.: Catalytic asymmetric cationic shifts of aliphatic hydrocarbons. Nature 625, S. 287 - 292 (2024)

Harbor-Collins, H.; Sabba, M.; Bengs, C.; Moustafa, G.; Leutzsch, M.; Levitt, M. H.: NMR spectroscopy of a ¹⁸O-labeled rhodium paddlewheel complex: Isotope shifts, ¹⁰³Rh–¹⁰³Rh spin–spin coupling, and ¹⁰³Rh singlet NMR. The Journal of Chemical Physics 160 (1), 014305 (2024)