Publications and Reports of the NMR Department

Korber, J. N.; Wille, C.; Leutzsch, M.; Fürstner, A. From the Glovebox to the Benchtop: Air-Stable High Performance Molybdenum Alkylidyne Catalysts for Alkyne Metathesis. Journal of the American Chemical Society 2023, 145, 26993–27009.

Moon, H. W.; Wang, F.; Bhattacharyya, K.; Planas, O.; Leutzsch, M.; Nöthling, N.; Auer, A. A.; Cornella, J. Mechanistic Studies on the Bismuth-Catalyzed Transfer Hydrogenation of Azoarenes. Angewandte Chemie International Edition 2023, 62, e202313578.

Tsuruta, T.; Spinnato, D.; Moon, H. W.; Leutzsch, M.; Cornella, J. Bi-Catalyzed Trifluoromethylation of C(Sp²)–H Bonds under Light. Journal of the American Chemical Society 2023, 145, 25538–25544.

Singh, V. K.; Zhu, C.; De, C. K.; Leutzsch, M.; Baldinelli, L.; Mitra, R.; Bistoni, G.; List, B. Taming Secondary Benzylic Cations in Catalytic Asymmetric S_N1 Reactions. Science 2023, 382, 325–329.

Palme, P. R.; Goddard, R.; Leutzsch, M.; Richter, A.; Imming, P.; Seidel, R. W. Structural Elucidation of the Triethylammonium Betaine of Squaric Acid. Molbank 2023, 2023, M1737.

Harbor-Collins, H.; Sabba, M.; Moustafa, G.; Legrady, B.; Soundararajan, M.; Leutzsch, M.; Levitt, M. H. The ¹⁰³Rh NMR Spectroscopy and Relaxometry of the Rhodium Formate Paddlewheel Complex. The Journal of Chemical Physics 2023, 159, 104307.

Mato, M.; Bruzzese, P. C.; Takahashi, F.; Leutzsch, M.; Reijerse, E. J.; Schnegg, A.; Cornella, J. Oxidative Addition of Aryl Electrophiles into a Red-Light-Active Bismuthinidene. Journal of the American Chemical Society 2023, 145, 18742–18747.

Lindner, M. M.; Alachraf, M. W.; Mitschke, B.; Schulze, P.; Leutzsch, M.; List, B. Toward a Formyl-to-Phenyl Conversion: An Unexpected Photochemical Fulvene-Rearrangement. Angewandte Chemie International Edition 2023, 62, e202303119.

Schwengers, S. A.; Gerosa, G. G.; Amatov, T.; Yasukawa, N.; Brunen, S.; Leutzsch, M.; Mitschke, B.; Shevchenko, G. A.; List, B. Direct Regioselective Dehydrogenation of α-Substituted Cyclic Ketones. Angewandte Chemie International Edition 2023, 62, e202307081.

Pang, Y.; Leutzsch, M.; Nöthling, N.; Cornella, J. Dihydrogen and Ethylene Activation by a Sterically Distorted Distibene. Angewandte Chemie International Edition 2023, 62, e202302071.

Yang, X.; Kuziola, J.; Béland, V. A.; Busch, J.; Leutzsch, M.; Burés, J.; Cornella, J. Bismuth-Catalyzed Amide Reduction. Angewandte Chemie International Edition 2023, 62, e202306447.

Mato, M.; Spinnato, D.; Leutzsch, M.; Moon, H. W.; Reijerse, E. J.; Cornella, J. Bismuth Radical Catalysis in the Activation and Coupling of Redox-Active Electrophiles. Nature Chemistry 2023, 15, 1138–1145.

Brunen, S.; Mitschke, B.; Leutzsch, M.; List, B. Asymmetric Catalytic Friedel–Crafts Reactions of Unactivated Arenes. Journal of the American Chemical Society 2023, 145, 15708–15713.

Pang, Y.; Nöthling, N.; Leutzsch, M.; Kang, L.; Bill, E.; van Gastel, M.; Reijerse, E.; Goddard, R.; Wagner, L.; SantaLucia, D. J.; DeBeer, S.; Neese, F.; Cornellà, J. Synthesis and Isolation of a Triplet Bismuthinidene with a Quenched Magnetic Response. Science 2023, 380, 1043–1048.

Chang, W.-C.; Randel, H.; Weyhermüller, T.; Auer, A. A.; Farès, C.; Werlé, C. A Cooperative Rhodium/Secondary Phosphine Oxide [Rh/P(O)NBu₂] Template for Catalytic Hydrodefluorination of Perfluoroarenes. Angewandte Chemie International Edition 2023, 62, e202219127.

Maji, R.; Ghosh, S.; Grossmann, O.; Zhang, P.; Leutzsch, M.; Tsuji, N.; List, B. A Catalytic Asymmetric Hydrolactonization. Journal of the American Chemical Society 2023, 145, 8788–8793.

Grimm, J. A. A.; Zhou, H.; Properzi, R.; Leutzsch, M.; Bistoni, G.; Nienhaus, J.; List, B. Catalytic Asymmetric Synthesis of Cannabinoids and Menthol from Neral. Nature 2023, 615, 634–639.

Yang, X.; Reijerse, E. J.; Nöthling, N.; SantaLucia, D. J.; Leutzsch, M.; Schnegg, A.; Cornella, J. Synthesis, Isolation, and Characterization of Two Cationic Organobismuth(II) Pincer Complexes Relevant in Radical Redox Chemistry. Journal of the American Chemical Society 2023, 145, 5618–5623.

Zhou, H.; Properzi, R.; Leutzsch, M.; Belanzoni, P.; Bistoni, G.; Tsuji, N.; Han, J. T.; Zhu, C.; List, B. Organocatalytic DYKAT of Si-Stereogenic Silanes. Journal of the American Chemical Society 2023, 145, 4994–5000.

Beyazay, T.; Belthle, K. S.; Farès, C.; Preiner, M.; Moran, J.; Martin, W. F.; Tüysüz, H. Ambient Temperature CO₂ Fixation to Pyruvate and Subsequently to Citramalate over Iron and Nickel Nanoparticles. Nature Communications 2023, 14, 570.