Publikationen und Berichte der NMR-Abteilung

Guillén, M.; Leutzsch, M.; List, B. Catalytic Asymmetric Cycloaddition of Olefins with In Situ Generated N-Boc-Formaldimine. Journal of the American Chemical Society 2024, 146, 32292–32297.

Scharf, M. J.; Tsuji, N.; Lindner, M. M.; Leutzsch, M.; Lõkov, M.; Parman, E.; Leito, I.; List, B. Highly Acidic Electron-Rich Brønsted Acids Accelerate Asymmetric Pictet–Spengler Reactions by Virtue of Stabilizing Cation–π Interactions. Journal of the American Chemical Society 2024, 146, 28339–28349.

Kuziola, J.; Nöthling, N.; Leutzsch, M.; Cornella, J. Synthesis and characterization of chlorotriarylbismuthonium salts. Chemical Communications 2024, 60, 10532–10535.

Peeters, M.; Baldinelli, L.; Leutzsch, M.; Caló, F. P.; Auer, A. A.; Bistoni, G.; Fürstner, A. In Situ Observation of Elusive Dirhodium Carbenes and Studies on the Innate Role of Carboxamidate Ligands in Dirhodium Paddlewheel Complexes: A Combined Experimental and Computational Approach. Journal of the American Chemical Society 2024, 146, 26466–26477.

Chugh, V.; Wu, J.; Leutzsch, M.; Randel, H.; Weyhermüller, T.; Auer, A. A.; Farès, C.; Werlé, C. Controlling hydrogen transfer dynamics in adaptive semihydrogenation of alkynes: Unveiling and directing outer- vs. inner-sphere mechanisms. Chem Catalysis 2024, 4, 101078.

Béland, V. A.; Nöthling, N.; Leutzsch, M.; Cornella, J. Activation and Catalytic Degradation of SF₆ and PhSF₅ at a Bismuth Center. Journal of the American Chemical Society 2024, 146, 25409–25415.

Lin, D. S.; Späth, G.; Meng, Z.; Wieske, L. H. E.; Farès, C.; Fürstner, A. Total Synthesis of the Norcembranoid Scabrolide B and Its Transformation into Sinuscalide C, Ineleganolide, and Horiolide. Journal of the American Chemical Society 2024, 146, 24250–24256.

Harbor-Collins, H.; Sabba, M.; Leutzsch, M.; Levitt, M. H. ¹H-enhanced ¹⁰³Rh NMR spectroscopy and relaxometry of ¹⁰³Rh(acac)₃ in solution. Magnetic Resonance 2024, 5, 121–129.

Luo, N.; Turberg, M.; Leutzsch, M.; Mitschke, B.; Brunen, S.; Wakchaure, V. N.; Nöthling, N.; Schelwies, M.; Pelzer, R.; List, B. The catalytic asymmetric polyene cyclization of homofarnesol to ambrox. Nature 2024, 632, 795–801.

Zheng, T.; Nöthling, N.; Wang, Z.; Mitschke, B.; Leutzsch, M.; List, B. A solid noncovalent organic double-helix framework catalyzes asymmetric [6 + 4] cycloaddition. Science 2024, 385, 765–770.

Karam, L.; Farès, C.; Weidenthaler, C.; Neumann, C. N. Expedited Synthesis of Metal Phosphides Maximizes Dispersion, Air Stability, and Catalytic Performance in Selective Hydrogenation. Angewandte Chemie International Edition 2024, 63, e202404292.

Han, J. T.; Tsuji, N.; Zhou, H.; Leutzsch, M.; List, B. Organocatalytic asymmetric synthesis of Si-stereogenic silacycles. Nature Communications 2024, 15, 5846.

Schulte, T.; Wang, Z.; Li, C.-C.; Hamad, A.; Waldbach, F.; Pampel, J.; Petzold, R.; Leutzsch, M.; Bahns, F.; Ritter, T. Ruthenium Phenoxo Complexes: An Isolobal Ligand to Cp with Improved Properties. Journal of the American Chemical Society 2024, 146, 15825–15832.

Spinnato, D.; Leutzsch, M.; Wang, F.; Cornella, J. Internal Atom Exchange in Oxazole Rings: A Blueprint for Azole Scaffold Evaluation. Synlett 2024, 35, 1015–1018.

Rütter, D.; van Gastel, M.; Leutzsch, M.; Nöthling, N.; SantaLucia, D.; Neese, F.; Fürstner, A. Molybdenum(VI) Nitrido Complexes with Tripodal Silanolate Ligands. Structure and Electronic Character of an Unsymmetrical Dimolybdenum μ-Nitrido Complex Formed by Incomplete Nitrogen Atom Transfer. Inorganic Chemistry 2024, 63, 8376–8389.

Mateos, J.; Schulte, T.; Behera, D.; Leutzsch, M.; Altun, A.; Sato, T.; Waldbach, F.; Schnegg, A.; Neese, F.; Ritter, T. Nitrate reduction enables safer aryldiazonium chemistry. Science 2024, 384, 446–452.

Hartmann, P.; Bohdan, K.; Hommrich, M.; Juliá, F.; Vogelsang, L.; Eirich, J.; Zangl, R.; Farès, C.; Jacobs, J. B.; Mukhopadhyay, D.; Mengeler, J. M.; Vetere, A.; Sterling, M. S.; Hinrichs, H.; Becker, S.; Morgner, N.; Schrader, W.; Finkemeier, I.; Dietz, K.-J.; Griesinger, C.; Ritter, T. Chemoselective umpolung of thiols to episulfoniums for cysteine bioconjugation. Nature Chemistry 2024, 16, 380–388.

Gehrke, L.; Bläker, C.; Pasel, C.; Farès, C.; Bathen, D. Structural and energetic characterization of silica-alumina gels for adsorption processes. Microporous and Mesoporous Materials 2024, 365, 112891.

Gui, X.; Sorbelli, D.; Caló, F. P.; Leutzsch, M.; Patzer, M.; Fürstner, A.; Bistoni, G.; Auer, A. A. Elucidating the Electronic Nature of Rh-based Paddlewheel Catalysts from ¹⁰³Rh NMR Chemical Shifts: Insights from Quantum Mechanical Calculations. Chemistry – A European Journal 2024, 30, e202301846.

Wakchaure, V. N.; DeSnoo, W.; Laconsay, C. J.; Leutzsch, M.; Tsuji, N.; Tantillo, D. J.; List, B. Catalytic asymmetric cationic shifts of aliphatic hydrocarbons. Nature 2024, 625, 287–292.