Publikationen von Markus Leutzsch

Pang, Y.; Leutzsch, M.; Nöthling, N.; Cornella, J. Catalytic Activation of N₂O at a Low-Valent Bismuth Redox Platform. Journal of the American Chemical Society 2020, 142, 19473–19479.

Barsu, N.; Leutzsch, M.; Fürstner, A. Ruthenium-Catalyzed trans-Hydroalkynylation and trans-Chloroalkynylation of Internal Alkynes. Journal of the American Chemical Society 2020, 142, 18746–18752.

Zhou, H.; Bae, H. Y.; Leutzsch, M.; Kennemur, J. L.; Bécart, D.; List, B. The Silicon−Hydrogen Exchange Reaction: A Catalytic σ‑Bond Metathesis Approach to the Enantioselective Synthesis of Enol Silanes. Journal of the American Chemical Society 2020, 142, 13695–13670.

Dagys, L.; Ripka, B.; Leutzsch, M.; Moustafa, G. A. I.; Eills, J.; Colell, J. F. P.; Levitt, M. H. Geminal parahydrogen-induced polarization: accumulating long-lived singlet order on methylene proton pairs. Magnetic Resonance 2020, 1, 175–186.

Ghosh, S.; Das, S.; De, C. K.; Yepes, D.; Neese, F.; Bistoni, G.; Leutzsch, M.; List, B. Strong and Confined Acids Control Five Stereogenic Centers in Catalytic Asymmetric Diels–Alder Reactions of Cyclohexadienones with Cyclopentadiene. Angewandte Chemie International Edition 2020, 59, 12347–12351.

Hillenbrand, J.; Leutzsch, M.; Yiannakas, E.; Gordon, C. P.; Wille, C.; Nöthling, N.; Copéret, C.; Fürstner, A. “Canopy Catalysts” for Alkyne Metathesis: Molybdenum Alkylidyne Complexes with a Tripodal Ligand Framework. Journal of the American Chemical Society 2020, 142, 11279–11294.

Ma, Y.; Pang, Y.; Chabbra, S.; Reijerse, E. J.; Schnegg, A.; Niski, J.; Leutzsch, M.; Cornella, J. Radical C−N Borylation of Aromatic Amines Enabled by a Pyrylium Reagent. Chemistry – A European Journal 2020, 26, 3738–3743.

Estes, D. P.; Leutzsch, M.; Schubert, L.; Bordet, A.; Leitner, W. Effect of Ligand Electronics on the Reversible Catalytic Hydrogenation of CO₂ to Formic Acid Using Ruthenium Polyhydride Complexes: A Thermodynamic and Kinetic Study. ACS Catalysis 2020, 10, 2990–2998.

Planas, O.; Wang, F.; Leutzsch, M.; Cornella, J. Fluorination of arylboronic esters enabled by bismuth redox catalysis. Science 2020, 367, 313–317.

Shmool, T. A.; Woodhams, P. J.; Leutzsch, M.; Stephens, A. D.; Gaimann, M. U.; Mantle, M. D.; Kaminski Schierle, G. S.; van der Walle, C. F.; Zeitler, J. A. Observation of high-temperature macromolecular confinement in lyophilised protein formulations using terahertz spectroscopy. International Journal of Pharmaceutics: X 2019, 1, 100022.

Hillenbrand, J.; Leutzsch, M.; Fürstner, A. Molybdenum Alkylidyne Complexes with Tripodal Silanolate Ligands: The Next Generation of Alkyne Metathesis Catalysts. Angewandte Chemie, International Edition 2019, 58, 15690–15696.

Biberger, T.; Gordon, C.; Leutzsch, M.; Peil, S.; Guthertz, A.; Copéret, C.; Fürstner, A. Alkyne gem‐Hydrogenation: Formation of Pianostool Ruthenium Carbene Complexes and Analysis of Their Chemical Character. Angewandte Chemie International Edition 2019, 58, 8845–8850.

Leutzsch, M.; Sederman, A. J.; Gladden, L. F.; Mantle, M. D. In situ reaction monitoring in heterogeneous catalysts by a benchtop NMR spectrometer. Magnetic Resonance Imaging 2019, 56, 138–143.

Ripka, B.; Eills, J.; Kouřilová, H.; Leutzsch, M.; Levitt, M. H.; Münnemann, K. Hyperpolarized fumarate via parahydrogen. Chemical Communications 2018, 54, 12246–12249.

Leutzsch, M.; Falkowska, M.; Hughes, T.-L.; Sederman, A. J.; Gladden, L. F.; Mantle, M. D.; Youngs, T. G. A.; Bowron, D.; Manyar, H.; Hardacre, C. An integrated total neutron scattering – NMR approach for the study of heterogeneous catalysis. Chemical Communications 2018, 54, 10191–10194.

Guthertz, A.; Leutzsch, M.; Wolf, L. M.; Gupta, P.; Rummelt, S. M.; Goddard, R.; Farès, C.; Thiel, W.; Fürstner, A. Half-​Sandwich Ruthenium Carbene Complexes Link trans-​Hydrogenation and gem-​Hydrogenation of Internal Alkynes. Journal of the American Chemical Society 2018, 140, 3156–3169.

Höfler, D.; van Gemmeren, M.; Wedemann, P.; Kaupmees, K.; Leito, I.; Leutzsch, M.; Lingnau, J. B.; List, B. 1,1,3,3-Tetratriflylpropene (TTP): A Strong, Allylic C–H Acid for Brønsted and Lewis Acid Catalysis. Angewandte Chemie International Edition 2017, 56, 1411–1415.

Monaco, M. R.; Fazzi, D.; Tsuji, N.; Leutzsch, M.; Liao, S.; Thiel, W.; List, B. The Activation of Carboxylic Acids via Self-Assembly Asymmetric Organocatalysis: A Combined Experimental and Computational Investigation. Journal of the American Chemical Society 2016, 138, 14740–14749.

Zhang, Z.; Bae, H. Y.; Guin, J.; Rabalakos, C.; van Gemmeren, M.; Leutzsch, M.; Klussmann, M.; List, B. Asymmetric counteranion-directed Lewis acid organocatalysis for the scalable cyanosilylation of aldehydes. Nature Communications 2016, 7, 12478.

Kötzner, L.; Leutzsch, M.; Sievers, S.; Patil, S.; Waldmann, H.; Zheng, Y.; Thiel, W.; List, B. The Organocatalytic Approach to Enantiopure 2H- and 3H- Pyrroles: Inhibitors of the Hedgehog Signaling Pathway. Angewandte Chemie International Edition 2016, 55, 7693–7697.