Publications of Markus Leutzsch

Ouyang, J.; Maji, R.; Leutzsch, M.; Mitschke, B.; List, B. Design of an Organocatalytic Asymmetric (4 + 3) Cycloaddition of 2-Indolylalcohols with Dienolsilanes. Journal of the American Chemical Society 2022, 144, 8460–8466.

Zhou, H.; Zhou, Y.; Bae, H. Y.; Leutzsch, M.; Li, Y.; De, C. K.; Cheng, G.-J.; List, B. Organocatalytic Stereoselective Cyanosilylation of Small Ketones. Nature 2022, 605, 84–89.

Peil, S.; Gutiérrez González, A.; Leutzsch, M.; Fürstner, A. C–H Insertion Via Ruthenium Catalyzed Gem-Hydrogenation of 1,3-Enynes. Journal of the American Chemical Society 2022, 144, 4158–4167.

Obradors, C.; Mitschke, B.; Aukland, M. H.; Leutzsch, M.; Grossmann, O.; Brunen, S.; Schwengers, S. A.; List, B. Direct and Catalytic C-Glycosylation of Arenes: Expeditious Synthesis of the Remdesivir Nucleoside. Angewandte Chemie International Edition 2022, 61, e202114619.

Biberger, T.; Hess, S. N.; Leutzsch, M.; Fürstner, A. Hydrogenative Cycloisomerization and Sigmatropic Rearrangement Reactions of Cationic Ruthenium Carbenes Formed by Catalytic Alkyne Gem-Hydrogenation. Angewandte Chemie International Edition 2022, 61, e202113827.

Hillenbrand, J.; Korber, J. N.; Leutzsch, M.; Nöthling, N.; Fürstner, A. Canopy Catalysts for Alkyne Metathesis: Investigations into a Bimolecular Decomposition Pathway and the Stability of the Podand Cap. Chemistry – A European Journal 2021, 27, 14025–14033.

Amatov, T.; Tsuji, N.; Maji, R.; Schreyer, L.; Zhou, H.; Leutzsch, M.; List, B. Confinement-Controlled, Either Syn- or Anti-Selective Catalytic Asymmetric Mukaiyama Aldolizations of Propionaldehyde Enolsilanes. Journal of the American Chemical Society 2021, 143, 14475–14481.

Caló, F. P.; Bistoni, G.; Auer, A. A.; Leutzsch, M.; Fürstner, A. Triple Resonance Experiments for the Rapid Detection of ¹⁰³Rh NMR Shifts: A Combined Experimental and Theoretical Study into Dirhodium and Bismuth–Rhodium Paddlewheel Complexes. Journal of the American Chemical Society 2021, 143, 12473–12479.

Pang, Y.; Leutzsch, M.; Nöthling, N.; Katzenburg, F.; Cornella, J. Catalytic Hydrodefluorination Via Oxidative Addition, Ligand Metathesis, and Reductive Elimination at Bi(I)/Bi(III) Centers. Journal of the American Chemical Society 2021, 143, 12487–12493.

Hughes, T.-L.; Falkowska, M.; Leutzsch, M.; Sederman, A. J.; Mantle, M. D.; Headen, T. F.; Youngs, T. G. A.; Bowron, D. T.; Hardacre, C. Bulk and Confined Benzene-Cyclohexane Mixtures Studied by an Integrated Total Neutron Scattering and NMR Method. Topics in Catalysis 2021, 64, 722–734.

Rösler, T.; Ehmann, K. R.; Köhnke, K.; Leutzsch, M.; Wessel, N.; Vorholt, A. J.; Leitner, W. Reductive Hydroformylation with a Selective and Highly Active Rhodium Amine System. Journal of Catalysis 2021, 400, 234–243.

Haack, A.; Hillenbrand, J.; Leutzsch, M.; van Gastel, M.; Neese, F.; Fürstner, A. Productive Alkyne Metathesis with “Canopy Catalysts” Mandates Pseudorotation. Journal of the American Chemical Society 2021, 143, 5643–5648.

Properzi, R.; Kaib, P. S. J.; Leutzsch, M.; Pupo, G.; Mitra, R.; De, C. K.; Song, L.; Schreiner, P. R.; List, B. Catalytic Enantiocontrol over a non-Classical Carbocation. Nature Chemistry 2020, 12, 1174–1179.

Hillenbrand, J.; Leutzsch, M.; Gordon, C. P.; Copéret, C.; Fürstner, A. ¹⁸³W NMR Spectroscopy Guides the Search for Tungsten Alkylidyne Catalysts for Alkyne Metathesis. Angewandte Chemie International Edition 2020, 59, 21758–21768.

Le Vaillant, F.; Reijerse, E. J.; Leutzsch, M.; Cornella, J. Dialkyl Ether Formation at High-Valent Nickel. Journal of the American Chemical Society 2020, 142, 19540–19550.

Pang, Y.; Leutzsch, M.; Nöthling, N.; Cornella, J. Catalytic Activation of N₂O at a Low-Valent Bismuth Redox Platform. Journal of the American Chemical Society 2020, 142, 19473–19479.

Barsu, N.; Leutzsch, M.; Fürstner, A. Ruthenium-Catalyzed Trans-Hydroalkynylation and Trans-Chloroalkynylation of Internal Alkynes. Journal of the American Chemical Society 2020, 142, 18746–18752.

Zhou, H.; Bae, H. Y.; Leutzsch, M.; Kennemur, J. L.; Bécart, D.; List, B. The Silicon−Hydrogen Exchange Reaction: A Catalytic σ‑Bond Metathesis Approach to the Enantioselective Synthesis of Enol Silanes. Journal of the American Chemical Society 2020, 142, 13695–13670.

Dagys, L.; Ripka, B.; Leutzsch, M.; Moustafa, G. A. I.; Eills, J.; Colell, J. F. P.; Levitt, M. H. Geminal Parahydrogen-Induced Polarization: Accumulating Long-Lived Singlet Order on Methylene Proton Pairs. Magnetic Resonance 2020, 1, 175–186.

Ghosh, S.; Das, S.; De, C. K.; Yepes, D.; Neese, F.; Bistoni, G.; Leutzsch, M.; List, B. Strong and Confined Acids Control Five Stereogenic Centers in Catalytic Asymmetric Diels–Alder Reactions of Cyclohexadienones with Cyclopentadiene. Angewandte Chemie International Edition 2020, 59, 12347–12351.