Homogeneous Catalysis
Our group focuses on the development of new catalysis concepts within the areas of organocatalysis, transition metal catalysis, and, to some extent, biocatalysis. Since 1999, the List-group concentrates on enantioselective organocatalysis as a fundamental approach complementing biocatalysis and transition metal catalysis. We have a profound interest in developing “new reactions”, designing and identifying new principles for the development of organocatalysts, expanding the scope of already developed catalysts such as proline, using organocatalysis in the synthesis of natural products and pharmaceuticals, and also investigating the mechanism by which organocatalysts activate their substrates. Furthermore, in 2005 our group has first conceptualized another approach to asymmetric catalysis, namely asymmetric counteranion directed catalysis (ACDC). This idea has not only progressed within the department but also at other institutions around the globe into a general strategy for asymmetric synthesis applied in organocatalysis as well as in transition metal catalysis and Lewis acid catalysis.
Prof. Dr. Benjamin List
- 2012-2014
- Managing Director at the Max-Planck-Institut für Kohlenforschung
- since 2005
- Director at the Max-Planck-Institut für Kohlenforschung
- since 2005
- Scientific member of the Max-Planck-Society
- since 2004
- Honorary Professor at the University of Cologne
- 2003–2005
- Group Leader at the Max-Planck-Institut für Kohlenforschung
- 1999–2003
- Assistant Professor (Tenure Track), Scripps Research Institute, La Jolla, USA
- 1997–1998
- Post-Doc, Scripps Research Institute, La Jolla, USA
- 1997
- PhD, University Frankfurt (J. Mulzer)
- 1993
- Chemistry Diplom, Free University Berlin
- 1968
- Born in Frankfurt/Germany
- 2017
- Ta-shue Chou Lectureship, Institute of Chemistry, Academia Sinica, Taipei, Taiwan
- 2015
- Gottfried Wilhelm Leibniz-Prize
- 2015
- Carl Shipp Marvel Lectures, University of Illinois at Urbana-Champaign, USA
- 2014
- Thomson Reuters Highly Cited Researcher
- 2014
- Cope Scholar Award, USA
- 2013
- Ruhrpreis, Mülheim, Germany
- 2013
- Mukaiyama Award 2013
- 2013
- Horst-Pracejus-Preis
- 2012
- Otto-Bayer-Preis
- 2012
- Novartis Chemistry Lectureship Award
- 2011
- Boehringer-Ingelheim Lectureship, Harvard University, USA
- 2011
- ERC Advanced Grant
- 2009
- Thomson Reuters Citation Laureate
- 2009
- Organic Reactions Lectureship, USA
- 2009
- Boehringer-Ingelheim Lectureship, Canada
- 2008
- Visiting Professor at Sungkyunkwan University, Korea
- 2007
- AstraZeneca Award in Organic Chemistry
- 2007
- 2007 OBC-Lecture Award
- 2007
- Award of the Fonds der Chemischen Industrie
- 2006
- 100 Masterminds of Tomorrow, Germany
- 2006
- JSPS Fellowship Award, Japan
- 2006
- Wiechert Lectureship, FU-Berlin, Germany
- 2005
- Novartis Young Investigator Award
- 2005
- AstraZeneca European Lecturer 2005
- 2005
- Visiting Professor at Gakushuin University, Tokyo/Japan
- 2005
- The Society of Synthetic Chemistry, Japan: 2005 Lectureship Award
- 2004
- Lieseberg-Price of the University of Heidelberg
- 2004
- "Lecturer's Award" of the Fonds der Chemischen Industrie
- 2004
- Degussa Prize for Chirality in Chemistry
- 2003
- Carl-Duisberg-Memorial Award of the German Chemical Society
- 2000
- Synthesis-Synlett Journal Award
- 1997
- Feodor-Lynen Fellowship of the Alexander von Humboldt Foundation
- 1994
- NaFöG-Award from the City of Berlin
-
University of Cologne
Lectures "Organocatalysis"
- since 2015
- Editor-in-Chief "Synlett", Thieme
- since 2011
- Regional Editor "Synlett", Thieme
- since 2010
- Member of the Editorial Advisory Panel "Nature Communications"
- since 2008
- Member of the Editorial Advisory Board "Beilstein Journal of Organic Chemistry"
- since 2005
- Editor "Synfacts", Thieme
- 2005-2011
- Programme Coordinator of the DFG Priority Programme SPP1179
- 2008-2009
- Editor: "Asymmetric Organocatalysis", Topics in Current Chemistry
- 2006
- Editor: "Organocatalysis", Chemical Reviews
- 2004
- Co-Editor, Special Edition: "Organocatalysis", Adv. Synth. Cat
-
Dr. Manuel van Gemmeren who worked until February 2015 in the department of Homogeneous Catalysis has just received two prestigious awards for his outstanding research work. At the annual meeting of the Max Planck Society in Saarbrücken he was honoured with the Otto Hahn Medal and the Otto Hahn award. The awards were granted for his development of exceptionally active and selective organocatalysts.
Dr. Mattia Monaco from List Group is finalist for the 2016 Reaxys PhD Prize
Dr. Mattia Monaco, who worked until January 2016 in the List Group at the Max-Planck-Insitut für Kohlenforschung, is one of the 45 finalists for the 2016 Reaxys PhD Prize. The team of Reaxys received nearly 450 submissions with top class quality.
The representative paper of Dr. Mattia Monaco is entitled: "Activation of Carboxylic Acids in Asymmetric Organocatalysis" published in Angewandte Chemie, 2014.Ben List ist very proud of his former PhD-student and sends congratulations.
Again within a few months, the research work of Benjamin List, director at the Max-Planck-Institut für Kohlenforschung and leader of the department for Homogeneous Catalysis, was honoured with one of the most important and highly respected research awards. After recently receiving the prestigious Gottfried Wilhelm Leibniz Prize from the DFG (Deutsche Forschungsgemeinschaft) the 48-year-old researcher was now awarded with the ERC Advanced Grant from the European Research Council. Both the ERC Advanced Grant as well as the Gottfried Wilhelm Leibniz Prize include research funding of up to € 2.5 million.
These are great news for the Max-Planck-Institut für Kohlenforschung in Mülheim and also for Benjamin List, who receives the ERC Advanced Grant for the second time. The grant will support the research work of List concerning the establishment of a new class of catalysts based on strong carbon-based acids.
Benjamin List revceives the Gottfried Wilhelm Leibniz Prize
The Gottfried Wilhelm Leibniz Prize is the most important research award in Germany. The Leibniz Programme, established in 1985, aims to improve the working conditions of outstanding researchers, expand their research opportunities, relieve them of administrative tasks, and help them employ particularly qualified early career researchers. A maximum of €2.5 million is provided per award.
-
University of Cologne
Lectures "Organocatalysis"
Research Topics
- Organocatalysis
-
Organocatalysis
Our research aims towards the invention of new strategies for the development of "perfect chemical reactions" that combine quantitative yields and high atom economy, while not requiring toxic solvents, protecting groups, heating, cooling, or inert gas atmosphere. We approach this ultimate goal by using selective catalysis based on small organic molecules. In recent years it has been demonstrated that these organocatalysts can be as efficient and selective as the more commonly used metal-based catalysts, resulting in an “explosive” research activity in this new and exciting area of Organocatalysis.
- Aminocatalysis
-
Aminocatalysis
We explore small-molecule amines as asymmetric catalysts for carbonyl transformations. “Asymmetric Aminocatalysis” functions by activating carbonyl compounds as iminium ions and enamines using a catalytic amount of an amine. Our strategy complements existing catalytic methods based on chiral acids and bases that typically involve metals. After our studies on the first asymmetric proline-catalyzed intermolecular aldol reaction in 2000, we realized that enamine catalysis has the potential to be a general strategy for the catalytic utilization of carbanion equivalents. Since then we have discovered several other transformations that can be catalyzed by primary or secondary amines. Currently our research aims towards the synthesis and identification of new catalyst structures to tackle further exciting and challenging problems and to discover new amine-catalyzed transformations.
- Brønsted Acid Catalysis
-
Brønsted Acid Catalysis
The number of reactions that can be catalyzed by Brønsted acids is enormous, and may even exceed that of reactions that cannot be catalyzed by Brønsted acids. In the light of this, Brønsted acid catalysis has become a core area of our research, focusing on the development and application of chiral organic Brønsted acids in asymmetric counteranion-directed catalysis (ACDC).
To date, various successful chiral Brønsted acids have emerged from our efforts, whose potential could be demonstrated in a large number of asymmetric transformations. Our SPINOL-derived phosphoric acids for instance have enabled an asymmetric Fischer-indolization, which could subsequently be applied to the enantioselective synthesis of helically chiral structures. The development of imidodiphosphates (IDPs) as confined Brønsted acids allowed for a crucial extension of our substrate scope to small molecules whose enantiofacial differentiation is more difficult, such as the substrates of the asymmetric sprioacetalization, or the selective sulfoxidation of thioethers. A chiral disulfonimide (DSI) was successfully applied in an enantioselective Torgov-cyclization.
- Organic Lewis Acid Catalysis
-
Organic Lewis Acid Catalysis
To date, the field of Lewis acid catalysis has been dominated by (transition) metal chemistry. To provide purely organic counterparts to these traditional catalytic systems we are dedicated to the synthesis and identification of organic Lewis acids. In 2009, we found that our chiral disulfonimides (DSIs) are not only excellent Brønsted acids, but turn into strong Lewis acids upon silylation. These in situ generated Lewis acids have enabled a variety of enantioselective “silyl-transfer” reactions with different silanes, including a three-component synthesis of homoallylic amines, the synthesis of dihydropyranones via a formal [4+2]-cycloaddition, as well as a Mukaiyama-aldol reaction, in which case catalyst loadings as little as 0.01 mol% proved sufficient.
Recently, we were able to extend the concept of organic Lewis acid catalysis to a highly enantio- and diastereoselective Diels-Alder reaction, in which only substoichiometric amounts of a silylating agent were sufficient to activate our newly developed C-H acid (binaphthyl-allyl-tetrasulfone, BALT).
- Asymmetric Couteranion Directed Catalysis (ACDC)
-
Asymmetric Couteranion Directed Catalysis (ACDC)
Most reactions proceed via charged intermediates and/or transition states. This allows to manipulate the course of a reaction and consequently also its stereochemical outcome by careful choice of a chiral counterion. In asymmetric phase transfer catalysis this concept is well established by using e.g. chiral quaternary ammonium cations. However, the anionic counterpart to this methodology, the use of chiral anions to influence the stereochemical outcome of reactions proceeding via cationic intermediates has been elusive for a long time. In 2006 we disclosed that the combination of a chiral phosphate anion and an achiral amine is a powerful catalytic system for the highly enantioselective transfer hydrogenation of enals in which the asymmetric induction is solely provided by the chiral counteranion. During the last years we have extended this concept to other organocatalytic as well as metal catalyzed transformations, focusing on innovative reactions and potentially new chiral counteranions.
- Synthesis of Natural Products and Biologically Active Compounds
-
Synthesis of Natural Products and Biologically Active Compounds
The ultimate goal of method development in organic synthesis is to provide useful and reliable tools for the synthesis of complex molecules such as natural products or biologically relevant compounds and to lead to a better understanding of the underlying principles. The value of a new method is often judged by the number of possible applications and the gain of knowledge it comes along with. In our group we are tackling chemical problems of asymmetric bond construction that are basically unsolved yet. Consequently a successfully developed new method should provide access to useful building blocks that can be used to easily ensemble complex molecules. Therefore the synthesis of natural products and pharmaceuticals is an important element of our research, not only to evaluate the potential of a new method, but also as a stimulus and source of inspiration towards new exciting discoveries.
Research Reports
- Research Report 2011 - 2013
- Research Report 2008 - 2010
- Research Report 2005 - 2007
- Research Report 2002 - 2004
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Staff
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Dr. Adair, Gareth
Postdoc, 08/2007 - 07/2008
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Dr. Alachraf, Mohammed Wasim
Postdoc, 04/2014 - 06/2016 ; Postdoc, 02/2017 - 03/2017
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Arlt, Jennifer
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Dr. Bae, Han Yong
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Dr. Blond, Aurélie
Postdoc, 01/15 - 03/2017
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Bock, Dominique Anna
PhD Student, 10/2010 - 03/2013
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Dr. Bondzic, Bojan
Postdoc, 02/2014 - 01/2015
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Dr. Bordeau, Guillaume
Postdoc, 01/2010 - 08/2011
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Dr. Buyck, Thomas
Postdoc, 03/2015 - 08/2016
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Dr. Chandler, Carley
Postdoc, 09/2006 - 09/2008
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Dr. Cheng, Xu
Postdoc, 12/2005 - 12/2008
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Dr. Chusov, Denis
Postdoc, 07/2009 - 07/2010
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Dr. Coric, Ilija
PhD Student, 09/2008 - 06/2013
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Correia, José Tiago Menezes
PhD Student, 01/15 - 01/16 : Visiting Doctoral Candidate 10/16 - 12/16
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Dr. Das, Sayantani
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Dašková,, Vanda
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Dr. De, Chandra Kanta
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de Fusco, Claudia
Visiting Doctoral Candidate, 04/2012 - 08/2012
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Dehn, Stefanie
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Dr. Demoulin, Nicolas
Postdoc, 01/2010 - 12/2012
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Diaz de los Bernardos Sanchez, Miriam
Visiting Doctoral Candidate, 08/2012 - 11/2012
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Díaz-Oviedo, Christian David
+49(0)208/306-2454
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Döhring, Arno
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Döhring, Camila
Student Assistant, 09/2008 - 11/2013
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Dr. Dupré, Nathalie
Postdoc, 04/2011 - 03/2013
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Eichert, Pina
Student Assistant, 06/2015 - 09/2015
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Erkkilä, Anniina
Guest Scientist, 10/2005 - 12/2005
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Dr. Fang, Yewen
Postdoc, 03/2009 - 09/2010
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Fröhlich, Laura
+49(0)208/306-2462
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Galiea, Pedro Llamas
Visiting Doctoral Candidate, 04/2005 - 07/2005
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Galzerano, Patrizia
Visiting Doctoral Candidate, 04/2008 - 12/2008
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Dr. Gandhi, Shikha
Postdoc, 10/2009 - 12/2012
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Garayalde Hernandez, David
Postdoc, 10/2012 - 09/2014
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Dr. Garcia Garcia, Patricia
Postdoc, 06/2007 - 05/2009
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Dr. Garcia Garcia, Pilar
Postdoc, 08/2008 - 01/2009 & 06/2009 - 06/2010
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Garczynski, Anika
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Gatzenmeier, Tim
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Gerosa, Gabriela
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Grossmann, Oleg
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Gruenwaldt, Caterina
Guest Scientist, 01/2008 - 03/2008; Intern, 07/2008 - 08/2008; Doctoral Candidate, 01/2010 - 03/2010 & 02/2011 - 05/2011
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Dr. Guin, Joyram
Postdoc, 07/2010 - 12/2012
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Dr. Halder, Rajkumar
Postdoc, 01/2007 - 01/2009
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Hannappel, Marianne
technician, 1968 - 04/2015
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Dr. Hechavarria Fonseca, Maria Teresa
Research Assistant, 08/2003 - 07/2007
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Hermsdorfer, Sylvia
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Dr. Hoffmann, Sebastian
PhD-Student, 05/2005 - 07/2008
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Höfler, Denis
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Dr. Huang, Shenlin
Postdoc, 01/2012 - 12/2014
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Dr. Huy, Peter
Postdoc, 04/2013 - 08/2013
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Dr. Hyodo, Kengo
Postdoc, 04/2013 - 03/2014
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Dr. James, Thomas
Postdoc, 08/2013 - 07/2015
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Jang, Hyeong Bin
Guest Scientist, 01/2009 - 02/2009 & 12/2009 - 02/2010
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Dr. Jiang, Gaoxi
Postdoc, 01/2009 - 12/2011
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Dr. Kaib, Philip
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Kaltsidis, Alexandra
+49(0)208/306-2411
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Dr. Kampen, Daniela
PhD-Student, 11/2005 - 06/2009
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Dr. Kasaplar Ozkal, Pinar
Postdoc, 10/2014 - 03/2016
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Kennemur, Jennifer
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Dr. Kim, Hyejin
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Dr. Kim, Ji Hye
PhD 09/2011 - 10/2015, Postdoc 11/2015 - 11/2015
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Konrad, David
Master-Student, 11/2012 - 08/2013
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Dr. Kötzner, Lisa
PhD Student 09/2012 - 04/2016 ; Postdoc 04/2016 - 07/2016
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Dr. Kundu, Dipti Sankar
Postdoc, 04/2013 - 06/2015
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Ky, Fiona
Guest Scientist, 02/2010 - 07/2010
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Dr. Ladepeche, Arnaud
Postdoc, 04/2006 - 09/2008
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Laws, Stephen
Visiting Doctoral Candidate 04/17 - 06/17
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Lay, Frank
PhD Student, 01/2007 - 06/2011
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Dr. Lee, Anna
PhD Student, 11/2008 - 11/2012
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Lee, Ji Woong
PhD Student, 09/2009 - 06/2013
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Dr. Lee, Sunggi
+49 (0)208/306-2458
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Dr. Leutzsch, Markus
PhD Student 11/2011 - 11/2015, Postdoc 12/2015 - 03/2016
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Dr. Li, Shen
Postdoc, 12/2009 - 11/2011
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Dr. Li, Xiaoguang
Postdoc, 11/2005 - 02/2006
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Dr. Liao, Saihu
PhD Student 09/2007 - 09/2011 & Postdoc 11/2014 - 03/2016
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Dr. Lifchits, Olga
PhD Student, 09/2008 - 04/2012
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Dr. Lindner, Monika
+49(0)208/306-2412
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Prof. Dr. List, Benjamin
+49(0)208/306-2410
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Liu, Luping
+49(0)208/306-2454
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Liu, Yuwei
PhD-Student (Stipendiat), 05/2007 - 02/2008
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Dr. Majumdar, Nilanjana
Postdoc 05/2016 - 05/2017
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Mandrelli, Francesca
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Dr. Manzano, Ruben
Guest Scientist, 07/2008 - 09/2008
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Martin, Nolwenn
PhD-Student, 01/2005 - 03/2009
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Dr. Martinez Cuezva, Alberto
Postdoc, 05/2010 - 04/2013
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Dr. Maulide, Nuno
Group Leader, 2009 - 2013
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Mayer, Sonja
PhD-Student, 04/2004 - 09/2007
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Meyer, Marc
+49(0)208/306-2464
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Dr. Michrowska-Pianowska, Anna Aleksandra
Postdoc, 05/2006 - 12/2008
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Dr. Mitra, Raja
+49(0)208/306-2459
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Dr. Monaco, Mattia Riccardo
PhD 11/2011 - 10/2015, Postdoc 11/2015 - 01/2016
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Dr. Moumne, Roba
Postdoc, 02/2006 - 01/2007
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Dr. Mukherjee, Santanu
Postdoc, 06/2006 - 05/2008
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Müller, Steffen
PhD Student, 02/2008 - 01/2012
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Dr. Musa, Sanaa
Postdoc, 10/2014 - 02/2015
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Dr. Nicoletti, Marcello
Postdoc, 11/2005 - 11/2006
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Oppelaar, Barry
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Dr. Ouyang, Jie
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Dr. Ozores Viturro, Lidia
Postdoc, 01/2005 - 12/2006
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Dr. Pan, Subhas Chandra
PhD Student 09/2005 - 07/2008, Postdoc 01/2011 - 09/2011 & guest scientist 05/2014 - 07/2014 & 11/2015 - 12/2015
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Dr. Pesciaioli, Fabio
Postdoc, 05/2011 - 07/2014; wiss. Mitarbeiter, 05/2014 - 07/2014
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Dr. Petkova, Desislava
Postdoc, 01/2016 - 07/2017
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Dr Pinto, Artur
Postdoc, 12/2007 - 05/2010
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Dr. Prévost, Sébastien
Postdoc, 01/2012 - 12/2013
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Dr. Properzi, Roberta
+49(0)208/306-2458
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Dr. Pupo, Gabriele
PhD 01/2013 - 12/2016, Postdoc 01/2016 - 01/2016
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Dr. Rampalakos, Konstantinos
Postdoc, 02/2008 - 08/2010
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Dr. Ratjen, Lars
PhD Student / Scientist, 10/2007 - 03/2012
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Dr. Reis, Ömer
Postdoc, 04/2005 - 03/2006
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Dr. Reisinger, Corinna Marie
PhD-Student, 01/2006 - 01/2010
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Dr. Rios-Torres, Ramon
Postdoc, 08/2004 - 03/2006
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Dr. Roy, Sutapa
Postdoc, 08/2011 - 08/2012
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Rujin, Svetlana
Student Assistant, 06/2009 - 05/2011
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Sadlowski, Natascha
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Scheel, Franziska
+49(0)208/306-2462
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Schreyer, Lucas
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Schwengers, Sebastian
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Dr. Seayad, Abdul Majeed
Postdoc, 12/2003 - 11/2005
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Seayad, Jayasree
AvH Stipendiat, 12/2003 - 11/2005
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Shevchenko, Grigory
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Dr. Sorto, Nohemy
Postdoc, 09/2013 - 08/2015
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Dr. Stadler, Michael
PhD-Student, 11/2004 - 12/2008
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Sulzer-Mosse, Sarah
Doctoral Candidate, 03/2006 - 03/2008
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Tan, Keng Foo
Guest Scientist 01/2015 - 07/2015
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Dr. Tap, Aurélien
Postdoc 02/2014 - 04/2016
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Dr. Tsui, Gavin Chit
Postdoc, 04/2013 - 01/2015
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Tsuji, Nobuya
+49(0)208/306-2457
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Dr. van Gemmeren, Manuel
PhD Student 01/2011 - 11/2014 & scientific staff 12/2014 - 02/2015
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van Thienen, Hendrik
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Dr. Varseev, Georgy
Postdoc, 10/2009 - 09/2012
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Dr. Vellalath, Sreekumar
Postdoc, 03/2008 - 11/2010
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Dr. Vignola, Nicola
Postdoc, 07/2003 - 12/2004
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Vlaar, Tjostil
Guest Scientist, 02/2010 - 08/2010
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Dr. Wakchaure, Vijay
+49(0)208/306-2440
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Walkamp, Pascal
Apprentice / Technician, 09/2005 - 08/2012
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Dr. Wang, Quinggang
Postdoc, 03/2011 - 03/2015
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Dr. Wang, Xingwang
Postdoc, 09/2005 - 08/2008
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Dr. Webber, Matthew
Postdoc, 04/2010 - 10/2012
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Wedemann, Petra
+49(0)208/306-2262
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Dr. Xie, Youwei
+49(0)208/306-2459
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Dr Yang, Jung-Woon
Postdoc, 10/2003 - 09/2006; Research Assistant, 10/2006 - 01/2009
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Dr. Zhang, Zhipeng
Scientific staff, 03/2011 - 02/2014
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Dr Zhou, Jian
Postdoc, 10/2005 - 09/2008
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Zumbansen, Kristina
PhD-Student, 10/2006 - 10/2010
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Zwerschke, Alexander
+49(0)208/306-2458
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